Michael is correct. Most of limestone is Calcium, Magnesium, and Carbonate. It is remains of million year old reefs. It in itself is 100% safe. The concern is what it mixed with in the ground. The brown color is either clay/mud or could be iron/ manganese, etc. Very few minerals are of any real concern. Copper, zinc, and heavy metals. These would create different colors yet in the rock. If it was mine, I would soak it in vinegar or very dilute muriatic acid to leach out the free metal ions. Then rinse very well and it should be 100% safe. These rocks are very popular with the freshwater cichlid keepers and other fresh water fish. It dissolves slowly in freshwater, would be neutral in the high PH we keep our tanks. If algae grew like crazy or corals would not grow or open, take it out. Base rock (dead live rock from the ocean) can be found pretty cheap if patient.