Be it know that Alk is difficult to test for and some Alk kits are FW and not SW. And there is allot of user error envoled.
I would assume that the rising Ca and Mg are caused by them being present as slightly soluble hydroxides which the test kits aren't picking up until they dissolve fully or react with dissolved CO2 or some other unknown factor.
Magnesium Hydroxide is almost insoluble, it is not like Kalk, calcium hydroxide. SeaChem uses Anhydrous salts which have dissolution issue at times and it just takes longer for them to dissolve and is why you are seeing the rise over time. Also, those numbers posted are within the "noise" factor of the test kit. Could some of that Mg++ be leaving a Mg(OH)2, yes. But remember OH- is part of the Alk.