Can the coral demand be high enough to pull this much Ca in 2 days?
It could, as the pH, Alk and Ca++ rise so does both their demands rise. In general, with Calcium using animals/plants, for every 1meq / l Alk loss there is a 20 ppm Calcium loss. So it you used up 1 meq / l Alk / day that is 20 ppm Calcium in one day. I have seen some that high and others lower. You are at about .75 meq / l / day which is 15 ppm Calcium / day, which is not uncommon. It just seems a little high for you.
Re-test to make sure.
The tests were double also.
Does this mean you did two tests, as you did not think the first one was correct ?
Do you see any white films anywhere, glass, heater or on the rock ? Your kalk is not mixng with the skimmer water anywhere is it.
Water changes ? A good approach is 10 % / wk or 30% / m
Since IO salt mix is slightly low for the parameters that I need to keep - shouldn't I maybe put some MG and Ca to the WC?
That is fine to do and many do it that way. It also relieves the pain in the ass of trying to bump it up in the tank. Others sup's no.