And, just so you guys know, a refractometer is not the end all device for accuracy, they dont know what things in the water are changing the angle of refraction, so its still not a real measure of salinity, but rather a sort of disolved ion count sort of thing
Livefor-buddy
Yes they are
Let me explain. There is no such device that really measures true salinity. Salinty is defined as the toal amount of all solid material dissolved in 1 kg of seawater, when all the carbonate has been converted to oxide, all the bromine and iodine is replaced by chlorine and all organic matter completly oxidized. The solid material, with no water, is expressed in grams, where salinity is given in g kg / l or ppt.
Lets look at a more migh-mouse version of it If you took a sample of seawater, that we know is 35 ppt and removed all the water you get 35 g kg / l by weight. This would give the following ion concentation by weight.
Cl- = 19.354
SO4-- = 2.712
Br- = 0.0673
F- = 0.0013
B = 0.0045
Na+ = 10.77
Mg++ = 1.290
Ca++ = .4121
K+ = .399
Sr++ = 0.0079
Total = 35 .00 g kg / l
This is something that takes a long time and is costly. Thus, there are 6 std measures that are use to replace this that are very accurate.
Chlorinity, where you measure the Cl- content which is 19 ppt for NSW. Chlorosity, which is the same but is expressed in g / l rather than in k kg / l. The Salinity can be mathamatically calculated for this by a constant, when using Chlorinity
S o/oo = 1.80655 x Clorintiy o/oo.
The other 4 stds are Refractometer, Electric Conductivity, Density and Specific gravity. The cuurent std is EC (Electric Conductivity) , which is the abiltiy for water to conduct electricity,
1. EC = 53,025 uS @ 77= 35 ppt
2. Density std @ 77F = 1.0237 =35 ppt
3. S.G = 1.02425. @ 77 using a std lab SG meter ( 59F) = 35 ppt
4. Refaction Idex, (RI) is 1.33940 @ 20C ( I do not have one for 77F). = 35 ppt
"IF" you took a std NSW sample, all of the meters/devices would give the above values but that is only NSW and we are NOT using NSW to calibrate things. If we where, we could use the same sample for all of these devices/meters to calibrate them. There are std. NSW solutions for this but they cost an arm and a leg :lol:
So, a refract is a std in seawater salinity measurement and they are very accurate, if calibrated correctly. Before EC it was the std.
A SeaTest Swing Arm is the best for anyone, if they know how to properly use it, clean it and get a good one. They are also not effected by temp. The problem with most swing arms, is that people blame the device and should be blaming themselvies. Out of all the swing arms that have been tested the SeaTest is the best. If my SeaTest sample reads 35 ppt and then I compare it to my $600 EC meter = 53mS = 35 ppt .....the same
Usually a SeaTest reads a little low but so do many of the refracts, as they are calibrated to NaCl, which is not NSW. So, you need to "bump" the refract cal solution sample, to get it to read properly, meaning a NaCl solution % that is = to NSW RI @ 35 ppt. This is all explained in Randy's articles
Reef Aquarium Salinity: Homemade Calibration Standards
http://reefkeeping.com/issues/2004-06/rhf/index.htm
Using Conductivity to Measure Salinity
http://www.aquariumfish.com/aquariumfish/detail.aspx?aid=1804
Specific Gravity Measurement
http://www.advancedaquarist.com/issues/jan2002/chemistry.htm
Nikki
That SaltyZOO calculator is only good if the hydrometer is calibrated to the same temp as the sample water, otherwise it is off and needs to be temp corrected.....that is floating bulb type hydrometers. A Tropic Marine is very accurate.
Refract cailbration temp is best if it is the same as the sample water temp, less error. Those with ATC usually do not have an issue with temp but I would do it at tank temp anyway.
The other issue we have been fighting for years and it will just not go away, is " my salintiy is 1.026", That is NOT Salinity but SG. People should start to use ppt as in 35 ppt, 34 ppt etc. as Salinity.