Holygral: as Mike stated, make sure you're using a very clean glass to take your readings. I used to use plastic tupperware, but have been told (and tested to find it true) that plastic container will give you a higher tds reading than a squeaky clean glass.
When taking your sample, let the RODI water run for a while before taking sample, as the 1st that comes out will have a higher tds reading than once the unit has been flowing for a bit.
With filters, RO membrane & DI resin all in good condition, the water after the DI resin should be between 0-1 tds...hopefully 0 or very close. At least that's what I've been reading for 75gpd RODI units.
It might be worthwhile to check with Buckeye to find out what they say their 100gpd RODI unit should produce in regards to tds.
hth,
rob