I have never heard of that as an issue. It is more on the order of having high Mg++ and trying to raise it to a higher level with high Alk. It is not much different than Ca++. Now if you dump in a ample amount of Mg++, when you have high Alk, the issue here is the local high Mg++ and Alk, which gives a precip of Magnesium Hydroxide. When you dump in a buffer and see that white cloud that is almost always Mg(OH)2. 99 % of the time it is the guy in the mirror dumping in to much at once. Lastly, fresh carbonate sand or media loves to pull out both Mg++ and Ca++ out of solution, of which we call Hi-Magnesium Calcite surface growths on the carbonate grains. Even if this is done slowly, there is an issue, as fresh grains have a high affinity for Mg++, until an equilibrium is reached or the grains get coated with organics, which is usually the case.